feat(config): job intervals live in sysconfig, every setting says when it applies, the unread SponsorBlock default goes

An interval override was a row of its own table beside the one store every other admin knob uses; it
is now the `job_interval_<job>` sysconfig key (migration 0110 copies them over and drops the table).
The Scheduler page stays its one editor: the Configuration page and the setup wizard neither list nor
write those keys, since a write there would skip the reschedule.

Each ConfigSpec now states `applies` (required, no default). Every key is `live`, held by a scan that
finds no read at import time; a `restart` key is refused until the page can say so. A second scan
requires a reader for every key on the Configuration page — `sponsorblock_default` had none since it
was added, so it leaves the registry, the translations and the store.

backend/app/config.py

@@ -274,8 +274,6 @@ class Settings(BaseSettings):
     job_run_retention_days: int = 180
     # On-disk layout: "plex" (Channel/Season YYYY/… [id].ext + .nfo/poster) or "flat".
     download_layout: DownloadLayout = "plex"
-    # Default SponsorBlock (skip sponsor segments) for new custom profiles.
-    sponsorblock_default: bool = False
 
     # --- Diagnostics / logging ---
     # BOOTSTRAP level only: the running level is the `log_level` admin knob (sysconfig), applied at